


What if the C-13 ratio is unknown?
If del C-13 has not been measured for a given
sample, it can be estimated on the basis of thousands of such measurements
that have already been reported. However, the estimate contributes an additional
degree of uncertainty that is reflected by an error term in the correction
formulae. Corrections for isotopic fractionation in commonly dated materials
are summarized below:
|
Material |
del C-13 |
Correction± error |
| peat, humus | -27 | -35 ± 95 |
| charcoal, wood | -25 | 0 |
| marine mammal fat | -23 | 20 ± 35 |
| terrestrial collagen | -20 | 80 ± 20 |
| bison collagen | -20 | 80 ± 20 |
| human collagen | -19 | 100 ± 20 |
| marine collagen | -15 | 160 ± 20 |
| maize | -10 | 245 ± 20 |
| bone apatite | -10 | 245 ± 35 |
| freshwater shells | -8 | 275 ± 50 |
| marine shells | 0 | 410 ± 70 |
It is important to note that the formulae for
bison collagen and human collagen yield only minimum corrections. In the
case of bison, one cannot know, unless del C-13 has been measured, the
proportion of C4 plants that comprised the animal’s diet. The estimated
value, -20 parts per mil, yields an adequate correction only if the animal
never consumed C4 plants. Likewise, the estimated value for human collagen,
-19 parts per mil, yields an adequate correction for humans that consumed
no marine resources, no C4 plant-eating bison, and no corn. Increases in
any of these dietary resources would enrich the C-13 ratio above -19 and
render the age correction too small by 16 years for every part per mil
change in the ratio.
Further reading:
Stuiver, M. and Polach, H.A.
1977 Reporting of 14C data. Radiocarbon 19(3): 355-363.