


How are radiocarbon dates normalized?
Normalization is a correction for isotopic
fractionation. It is based on the ratio between C-12 and C-13, called del
C-13, which is expressed in parts per mil (parts per thousand) with respect
to a standard known as Pee Dee Belemnite (PDB). Belemnite is a calcareous
Cretaceous fossil found in Pee Dee, South Carolina. Most organic materials
contain less C-13 than PDB, yielding negative values for del C-13. For
example, most C3 plants have C-13 ratios near -25 parts per mil, whereas
C-13 ratios in C4 plants are in the range of -10 to -12.5 parts per mil.
Herbivores are less selective against the heavier isotopes, and their bone
collagen is enriched by 5 parts per mil in relation to their diet. Yet
another change occurs in carnivores whose bone collagen is enriched by
an additional 1 part per mil. Marine plants are similar to C3 plants, but
they obtain their carbon from dissolved oceanic bicarbonates that differ
from the atmosphere in their isotope ratios, and this difference is passed
up the marine food chain.
Radiocarbon dates can be normalized to any chosen value, and the value
chosen by international convention is -25 parts per mil based on an internationally
accepted oak standard. Every part per mil difference from -25 is equivalent
to 16 years. For example, bone collagen from marine mammals commonly has
a C-13 ratio of -15 parts per mil. That difference of 10 parts per mil
from the oak standard means that the age of the marine mammal bone can
be normalized by adding 160 years to its measured age.
Further reading:
Stuiver, M. and Polach, H.A.
1977 Reporting of 14C data. Radiocarbon 19(3): 355-363.